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mycofactocin biosynthesis

State Icon Reaction EC-Number Confidence maximal confidence score from EnzymeDetector
UDP-glucose + MMFT-6 <=> MMFT-7 + UDP + H+ 2.4.1.M64

C-terminal_[mycofactocin_precursor_peptide]-glycyl-L-valyl-L-tyrosine + S-adenosyl-L-methionine <=> C-terminal_[mycofactocin_precursor_peptide]-glycyl-L-valyl-decarboxylated_L-tyrosine + CO2 + 5''-deoxyadenosine + L-methionine 1.3.98.g

UDP-glucose + MMFT-2 <=> MMFT-3 + UDP + H+ 2.4.1.M64

UDP-glucose + PMFT <=> MFT-1 + UDP + H+ 2.4.1.M64

UDP-glucose + MMFT-3 <=> MMFT-4 + UDP + H+ 2.4.1.M64

UDP-glucose + MFT-1 <=> MFT-2 + UDP + H+ 2.4.1.M64

UDP-glucose + MMFT-8 <=> MMFT-9 + UDP + H+ 2.4.1.M64

UDP-glucose + MMFT-5 <=> MMFT-6 + UDP + H+ 2.4.1.M64

S-adenosyl-L-methionine + MFT-2 <=> MMFT-2 + S-adenosyl-L-homocysteine + H+ 2.1.1

UDP-glucose + MMFT-4 <=> MMFT-5 + UDP + H+ 2.4.1.M64

C-terminal_[mycofactocin_precursor_peptide]-glycyl-3-amino-5-[(4-hydroxyphenyl)methyl]-4,4-dimethylpyrrolidin-2-one + H2O <=> C-terminal_[mycofactocin_precursor_peptide]-glycine + 3-amino-5-[(4-hydroxyphenyl)methyl]-4,4-dimethyl-2-pyrrolidin-2-one 3.4.14.b

C-terminal_[mycofactocin_precursor_peptide]-glycyl-3-amino-5-[(4-hydroxyphenyl)methyl]-4,4-dimethylpyrrolidin-2-one + 5''-deoxyadenosine + L-methionine + H+ + acceptor <=> C-terminal_[mycofactocin_precursor_peptide]-glycyl-L-valyl-decarboxylated_L-tyrosine + S-adenosyl-L-methionine + reduced_acceptor 4.1.99.q

UDP-glucose + MMFT-7 <=> MMFT-8 + UDP + H+ 2.4.1.M64

5-[(4-hydroxyphenyl)methyl]-3-imino-4,4-dimethylpyrrolidin-2-one + H2O + H+ <=> PMFT + NH3 not assigned

3-amino-5-[(4-hydroxyphenyl)methyl]-4,4-dimethyl-2-pyrrolidin-2-one + O2 <=> 5-[(4-hydroxyphenyl)methyl]-3-imino-4,4-dimethylpyrrolidin-2-one + H2O2 + H+ not assigned

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